在可持续能源系统快速发展的背景下,电化学储能技术正受到广泛关注。其中,水系锌离子电池(AZIBs) 因其具有高理论容量、丰富的锌资源和固有安全性,成为下一代储能器件的重要候选技术。然而,锌金属负极存在的不可控析氢反应(HER)、腐蚀及枝晶生长等问题严重制约了AZIBs的进一步发展和实际应用。
目前,锌粉基阳极面临着一些严峻的挑战,包括严重的副反应和不均匀的Zn的沉积/剥离。这些问题导致锌负极可逆性差和锌 ...
水系锌金属电池(AZMBs)因具有安全性高、成本低和环境友好性等优点而有望取代锂离子电池。然而,由不稳定的电解质-负极界面引起的析氢反应(HERs)和腐蚀反应严重阻碍了AZMBs的实际应用。为了减轻电解液-电极界面的不可逆副反应,必须减少锌的腐蚀并提 ...
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Research Institute of Chemical Defense, Beijing 102205, P.R. China ...
Zhejiang Key Laboratory of Safety Engineering and Technology Research, Zhejiang Academy of Emergency Management Science, Hangzhou 310012, China ...