The original plan of the research groups of Dr. habil. Christian Hering-Junghans and Prof. Torsten Beweries at the Rostock ...
Adduct formation proceeds via the reaction of the amino group(s) on ethidium with the ring-opened aldehyde residue of the AP site in DNA to yield an imine. Ethidium-AP adducts may form under a variety ...
手性叔丁基亚磺酰胺是一个优质的不对称辅助剂。手性Ellman亚胺 (Ellman’s Imine)与亲核试剂反应的话可以得到高非对映选择性产物。尽管手性叔丁基磺酰胺参与反应时需要加入化学当量,属于较为原始的手性辅基控制,但经过不断的改进,这种化合物的合成技术已十分纯熟,且制备成本很低,目前已得到商品化推广,并在学术研究及工业化生产中得到了广泛的应用。
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THE recently suggested theory of Pausacker and Schubert 1 involving free radicals in the Fischer indole synthesis appeared to us improbable. It seemed more likely that these experimental results ...