Advances in lipase-catalyzed esterification reactions
2013年12月1日 · It is widely accepted that lipase-catalyzed reactions (hydrolysis, esterification, etc.) can be described by a ping-pong bi-bi mechanism, which proceeds through the formation of an acyl-enzyme, as it is expressed in reaction Scheme 1 (as modified from Cleland, 1970).
Advances in lipase-catalyzed esterification reactions
This article presents a thorough and descriptive evaluation of the applied trends and perspectives concerning the enzymatic esterification, mainly for biofuel production; an emphasis is given on essential factors, which affect the lipase-catalyzed esterification reaction.
Lipase-catalyzed Reactions at Interfaces of Two-phase Systems …
More specifically, we investigate how the presence of a Sn-2 monoglyceride, which expels the lipase from the interface, affects the ability of the lipase to catalyze hydrolysis and esterification reactions with lipophilic substrates.
Stereoselective Promiscuous Reactions Catalyzed by Lipases
2022年2月28日 · The aim of this review, mainly focused on those lipase-catalyzed promiscuous reactions in which optically active products have been obtained, is to offer a current state of art together with a perspective in this field of asymmetric synthesis.
Lipase catalysis in organic solvents: advantages and applications
The present review describes the advantages of lipase-catalyzed reactions in organic solvents and various effects of organic solvents on their activity. Keywords: Lipase, Organic media, Biocatalysis, Transformations, Industrial applications
Lipase-catalyzed polyester synthesis – A green polymer chemistry
2010年1月20日 · A model expression of lipase-catalyzed reactions: (a) In vivo hydrolysis and (b) In vitro polymerization of monomers to produce a polyester molecule.
Lipase-Catalyzed Esterification - Taylor & Francis Online
2007年2月5日 · Lipases are versatile catalysts. In addition to their natural reaction of fat hydrolysis, lipases catalyze a plethora of other reactions such as esterification, amidation, and transesterification of esters as well as organic carbonates.
Promiscuity of Lipase‐Catalyzed Reactions for Organic Synthesis: A ...
2018年3月2日 · Advances in lipase promiscuity during the past decades demonstrate the augmentation of their application in green chemistry. This review gives an insightful overview of new dimensions of lipase catalysis and what more could be …
Ester synthesis in lipase-catalyzed reactions - ScienceDirect
1998年11月15日 · In addition to water, the media and support material are seldom inert and often interact with other factors affecting the reaction. Several methods of water removal and their effectiveness in lipase-catalyzed reactions are discussed.
Lipase-Catalyzed Synthesis of Astilbin Esters: Effect Mechanism
2024年10月7日 · Lipase-Catalyzed Synthesis of Astilbin Esters: Effect Mechanism of Key Reaction Factors and Physical Properties of Products. 38 Pages Posted: ... The isomerization reaction was found in the enzymatic transesterification reaction system, producing neoastilbin fatty acid esters. Subsequently, the pathway of isomerization reaction was investigated ...